[1]刘 畅.超高效液相色谱-质谱法测定大豆中磺酰脲类除草剂残留量的研究[J].黑龙江农业科学,2015,(07):124-126,138.[doi:10.11942/j.issn1002-2767.2015.07.0124]
　LIU Chang.Study on the Determination of Sulfonylurea Herbicide Residues in Soybeans by Ultra High Performance Liquid Chromatography Tandem Mass Spectrometry[J].HEILONGJIANG AGRICULTURAL SCIENCES,2015,(07):124-126,138.[doi:10.11942/j.issn1002-2767.2015.07.0124]
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超高效液相色谱-质谱法测定大豆中磺酰脲类除草剂残留量的研究

《黑龙江农业科学》[ISSN:1002-2767/CN:23-1204/S] 卷: 期数: 2015年07 页码: 124-126,138 栏目: 出版日期: 2015-07-10
Title:
Study on the Determination of Sulfonylurea Herbicide Residues in Soybeans by Ultra High Performance Liquid Chromatography Tandem Mass Spectrometry
文章编号:
1002-2767（2015）07-0124-03
作者:
刘 畅
哈尔滨市农产品质量安全检验检测中心，黑龙江 哈尔滨 150070
Author(s):
LIU Chang
Harbin City Agricultural Products Quality Safety Inspection Testing Center,Harbin,Heilongjiang 743000
关键词:
大豆; 磺酰脲类除草剂; 超高效液相色谱-质谱法
Keywords:
soybean;  sulfonylurea herbicides;  ultra high performance liquid chromatography tandem mass spectrometry
分类号:
O657.63
DOI:
10.11942/j.issn1002-2767.2015.07.0124
文献标志码:
A
摘要:
为了建立大豆中7种磺酰脲类除草剂残留量的测定方法。大豆样品先后经过乙腈提取、正己烷去脂、HLB固相萃取柱净化处理，超高效液相色谱串联四级杆质谱测定，外标法定量。结果表明：7种磺酰脲类除草剂在50~300 μg?L-1时具有良好的线性关系，相关系数均在0.99以上，加标回收率为71.2%~91.5%，相对标准偏差小于10%，可以满足大豆中多种磺酰脲类除草剂残留量的检测。
Abstract:
In order to establish determination method of 7 kinds of sulfonylurea herbicides in soybean.Samples were extracted with acetonitrile,defatted with hexane,cleaned with HLB SPE,and then detected by UPLCMS/MS with external standard method of quantitative.The results showed that the linear range was 50~300 μg?L-1，the correlation coefficients was above 0.99.The average recovery ranged from 71.2% to 91.5%，and the relative standard deviations below 10%，which could be accepted to determine the sulfonylurea herbicides in soybean.

参考文献/References:

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备注/Memo

收稿日期：2015-03-10
作者简介：刘畅（1988-），女，黑龙江省青冈县人，硕士，助理农艺师，从事农药残留检测研究。E-mail：y150030@126.com。

更新日期/Last Update: 2016-03-29