[1]马兴娟,费发源.ICP-AES法测定石灰性土壤中的有益元素有效磷[J].黑龙江农业科学,2016,(06):42-45.[doi:10.11942/j.issn1002-2767.2016.06.0042]
　MA Xing-juan,FEI Fa-yuan.Determination of Useful Element of the Effective Phosphorus in Calcareous Soil by ICP-AES[J].HEILONGJIANG AGRICULTURAL SCIENCES,2016,(06):42-45.[doi:10.11942/j.issn1002-2767.2016.06.0042]
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ICP-AES法测定石灰性土壤中的有益元素有效磷

《黑龙江农业科学》[ISSN:1002-2767/CN:23-1204/S] 卷: 期数: 2016年06 页码: 42-45 栏目: 出版日期: 2016-06-10
Title:
Determination of Useful Element of the Effective Phosphorus in Calcareous Soil by ICP-AES
文章编号:
1002-2767（2016）06-0042-04
作者:
马兴娟;  费发源
（青海省核工业地质局检测试验中心，青海 西宁 810016）
Author(s):
MA Xing-juan; FEI Fa-yuan
(Testing Centre in the Nuclear Geological survey of QingHai Province,Xining,Qinghai 810016)
关键词:
ICP-AES法; 石灰性土壤; 有益元素;  有效磷
Keywords:
ICP-AES; calcareous soil; useful element;  available phosphorus
分类号:
S151.9+5；O657.3
DOI:
10.11942/j.issn1002-2767.2016.06.0042
文献标志码:
A
摘要:
为寻求高效、大规模的土壤有效磷的测定方法，采用碳酸氢钠浸提ICP-AES测定石灰性土壤中有益元素中的有效磷含量，研究了浸提时间、浸提温度、样品稳定时间等因素对浸提结果的影响。结果表明：通过试验优选仪器参数和分析谱线，在选定波长为213.618 nm测定，国家一级标准物质的测定值与标准值相吻合，分析结果准确可靠，精密度和准确度都能很好的满足要求，检出限为0.18 mg?kg-1，标准加入的回收率在96.38%～103.3%。该法操作简单、快捷、无污染，能使有效磷的分析趋于自动化，使得高效、大规模的土壤有效磷的测定分析成为现实，可成功地适用于石灰性土壤样品中有效磷的测定，值得大面积的推广与应用。
Abstract:
In order to search for the efficient and large-sclae determination method of available phosphorus in soil，the available phosphorus in calcareous soil was determinated by sodium bicarbonate leaching ICP-AES.The effect of extraction time,extraction temperature and sample stability time on leaching were studied.The results showed that through the optimizing instrument parpmeter experiment and analysis spectral lines,wavelength was 213.618 nm,national standard material of measurements was in conformity with the standard values,the analysis results were accurate and reliable,precision and accuracy could well meet the requirements,the detection limit was 0.18 mg?kg-1 ,recovery of standard addition was between 96.38%~103.3%.The operation was simple,fast,no pollution,and lead to the automation analysis of the available phosphorus,made the large-scale to become a reality,the method of the determination of available phosphorus in soil analysis could be successfully applied to the determination of the available phosphorus in calcareous soil samples,the method was worthy of widespread popularization and application.

参考文献/References:

[1] 岩石矿物分析编委会．岩石矿物分析 ( 第四版第四分册 )[M] ． 北京: 地质出版社，2011: 878-884．

[2]Olsen S R，Cole C V，Watanabe F S，et al．Estimation of available phosphorus in soils by extraction with sodium bicarbonate[R]．United States Department of Agriculture Circular,1954:939.

[3]岩石矿物分析编委会．岩石矿物分析(第二分册)[M]．4版.北京:地质出版社，2011:376-389．

[4]王芹，徐清波，姚振琴.土壤有效磷的测定[J].仪器仪表与分析监测，2009（4）:36-40.

[5]沈志群，张琪，刘琳娟，等.碳酸氢钠浸提-钼锑钪分光光度法测定土壤中的有效磷[J].环境监控与预警，2011，3（5）:12-15.

[6]张雯雯，陈智文，李筱琳.测定石灰性土壤有效磷的影响因素分析[J].安徽农业科学，2010,38（9）:4717-4719.

[7]刘肃,李酉开.Mehlich 3通用浸提剂的研究[J].土壤学报,1995,32(2):132-141.

[8]沈仁芳,蒋柏藩.Mehlich 3 浸提剂与石灰性土壤有效磷的关系[J].土壤通报,1994,25(3): 141-142.

[9]李昆,代飞天,陈钢.土壤有效磷测定方法比较[C]/江荣风,杜森.首届全国测土配方施肥技术研讨会论文集.北京: 中国农业大学出版社,2007：123-129.〖ZK)〗

[10]〖ZK(#〗王明锐，袁友明，路磊.ICP-AES法测定过磷酸钙中有效磷的含量[J].光谱仪器与分析，2006，Z(1)：186-188.

[11]潘淑春，王雪莲，陈梅，等.全谱直读等离子体发射光谱法测定土壤中的有效磷[J].矿产综合利用，2015（3）:59-61.

[12]邵煜庭,马金占,甄清香.土壤有效磷、钾、锰、铜、铁的联合测定[J].土壤通报，1994,25(3):142-144.

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备注/Memo

收稿日期：2016-05-09

第一作者简介：马兴娟（1981-），女， 青海省西宁市人，学士，工程师，从事地球化学样品分析测试方法技术研究工作和岩矿测试研究。E-mail: 42617985@qq.com。

更新日期/Last Update: 2016-12-12